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Dr Clive Clayton holds the rank of Leading Professor in Materials
Science and Engineering at Stony Brook University where he has been
on the faculty since 1978. He is a Fellow of the Electrochemical
Society and has edited eight professional conference proceedings
and co-written nearly 200 publications concerned with the
application of surface science to fundamental and applied aspects
of materials. His research has recently developed in the direction
of green materials synthesis and analysis and ecoefficiency studies.
He has served as department Chair of Materials Science and
Engineering and Associate Dean of Engineering for research. In the
latter position he co-founded the Stony Brook University SPIR
program with Dean Yacov Shamash and has been Director for SPIR
since 1994. Dr Clayton also is the Director of the Institute for
Sustainable Development.
Degrees
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Ph.D. Materials Science University of Surrey UK
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1976
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B.Sc. (Hons).Materials Science University of Surrey UK
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1973
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Honors and Awards:
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Fellow, Electrochemical Society
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10/2004
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Monbusho International Scientific Research Program Fellowship (Kyoto University)
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1998
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Elected Member Bomische Physical Society
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1983
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Scientific Research Council Fellowship (UK)
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1973-1976
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Appointments: All Stony Brook University
| Leading Professor, Materials Science and Engineering | | 12/00-present |
| Director, Laboratory for Surface Analysis and Corrosion Science | | 1/78-present |
| Director, Center for Advanced Technical Assistance. | | 1/94-present |
| Assoc. Dean of Engineering (Research and Graduate Studies) | | 1/93- 12/97 |
| Chair, Department of Materials Science and Engineering, | | 1/91- 7 /93 |
| Professor | | 9/89- 12/00 |
| Associate Professor | | 9/82- 8/89 |
| Assistant Professor | | 9/78- 9/82 |
| Visiting Assistant Professor | | 6/77- 9/78 |
Administrative Appointments:
| Director, Institute for Sustainable Development | | 1/04-present |
| Director: Center for Advanced Technical Assistance (SPIR program) | | 7/94- present |
| Assoc. Dean of Engineering (Research and Graduate Studies) | | 1/93- 12/97 |
| Chair, Department of Materials Science and Engineering, | | 1/91- 7 /93 |
| Chair, Corrosion Division of the Electrochemical Society | | 10/00-10/02 |
| Member Advisory board of the BASF Corporation sponsored Rensselaer (NY) Ecological Education Center. | | 11/07- present |
| Member Advisory Board of Orphans International America | | 2/08- present |
Professional Associations: (past and present)
| Electrochemical Society (Past Chair of Corrosion Division) |
| Institute of Materials (London) |
| Chartered Engineer (London) |
| Bohmische Physical Society |
| American Vacuum Society |
| American Chemical Society |
Research Activities:
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Director of the Surface Analysis and Corrosion Science Laboratory
in the Department of Materials Science and Engineering at Stony
Brook. Developed this facility over the last 26 years into one of
the premier university surface analytical facilities. Facilities
available in this laboratory include four dual anode X-ray
Photoelectron Spectrometers One system uses a 1000A spot electron
beam and is capable of SEM imaging and Auger chemical mapping of
surfaces. Also located in this Laboratory are two Secondary Ion
Mass Spectrometers (SIMS) capable of static and dynamic analysis of
samples, including SIMS chemical mapping using a 0.2 micron spot
gallium ion beam. Thin film deposition facilities, incorporating
two saddle-field ion guns and one 1500 C effusion cell, for design
of prototype coatings and novel material compositions are also
available in the Laboratory. Diamond-like and nitride coatings are
being developed in collaboration with the Army research Laboratory
for wear resistance as a replacement for electroplated chromium.
This facility combined with a fully equipped. Electrochemical
laboratory has supported the research described in the publications
outlined in this document. Corrosion laboratory has extensive
facilities for corrosion testing that includes several
potentiostats, EIS measurements, bipotentiostats, rotating disk
electrodes etc.
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Funded Research Programs:
Equipment Award for Electron Spectrometer NSF 4/1/78 |
Ion Implantation Metallurgy ONR 6/1/77-8/31/83 |
Experimental Research on Characterizing Corrosion Properties of Ion Implanted M50 Bearing Alloy NRL 9/18/78-9/17/79 |
XPS Study of Passive Films Formed on 304 Stainless Steel BNL 11/9/79-7/11/80 |
Wear and Corrosive Properties of Ion Implanted Steel ONR 9/30/79-6/30/81 |
Corrosion Properties of Ion Intermixed 52100 Steel NRL 9/1/81-2/28/82 |
Passivity and The breakdown of Passivity of Stainless Steels NSF 8/1/81-9/30/84 |
Equipment Award: Acquisition of data Collection for Surface Analysis System NSF 12/15/81-11/30/82 |
Characterization of Ion Implanted Steels NRL 8/1/82-12/1/83 |
Travel Fellowship to Speak at NATO Conference-Trevi Italy ARO 9/1/83-8/31/84 |
Electron Spectroscopy and Diffraction Study of the Mechanism of Passivity of Ni- 20P Alloy SNL 3/1/85-8/31/87 |
Passivity Mechanisms in Stainless Steel: Mo-N Synergism ONR 6/1/85-9/30/88 |
Corrosion Behaviour of Amorphous Alloys formed by Ion Implantation ONR 6/30/84-6/29/85 |
Evaluation of the Bipolar Fixed Charge Mechanism of Passivity of Stainless Steel NSF 2/1/86-1/31/89 |
XPS Studies of The Passivity of a Series of Ni-20P-XCr Amorphous Alloys SNL 10/1/87-9/30/88 |
Passivity Mechanisms in The Stainless Steel Mo-N Synergism ONR 10/1/88-9/30/91 |
US-Swedish Cooperative Research: The Role of Alloy Interfacial Layers on Passivity NSF 2/1/90-1/31/93 |
Investigation into The Susceptibility of Corrosion Resistant Alloys to Biocorrosion ONR 9/30/92-9/29/95 |
Surface and Interface Characterization of Advanced Materials JSU/ARL 8/1/96-12/31/99 |
MURI '96: Mechanisms of Al-Alloy and Roles of Chromate AFOSR9/30/96-1/10/2001 |
Mechanisms of Military Coatings Degradation Strategic Environmental Research and Development Program (SERDP) DoD/DOE/EPA 1/1/99 |
Mechanisms of Radionuclide Hydroxycarboxilic and Interactions for Decontamination of Metallic Surfaces DOE 9/15/98-9/14/01 |
Corrosion Protective Coatings for Depleted Uranium Penetrator Systems US Army Research Office 9/26/01 - 9/25/04 |
Synergistic Effects of Multiple Environments on Composite Degradation NSF 8/15/02 - 8/14/05 |
Spectroscopic and Microscopic Study of the Nature of the Bonding of Heavy Metals and organic Contaminants to Soil and Sediments BASF 7/1/05-present |
Major Research Activity in the last 10 years:
Investigation into The Susceptibility of Corrosion Resistant Alloys to Biocorrosion
ONR 9/30/92-9/29/95
This project developed a rapid protocol for determining the
susceptibility of stainless steels to biocorrosion following
exposure to sulphate reducing bacteria and metabolic products of
the same. A model of biocorrosion was developed from
electrochemical and surface analytical analyses especially
developed for this study.
Surface and Interface Characterization of Advanced Materials
JSU/ARL 8/1/96-12/31/98
Diamond-like C-Si nanostructures were created by Ion Beam Assisted
Deposition at Stony Brook and at Aberdeen Proving Ground and were
subsequently studied by X-ray Induced Valence Band analysis and by
Infrared Microspectroscopy.
MURI '96: Mechanisms of Al-Alloy and Roles of Chromate
AFOSR9/30/96-1/10/2001
This program aims to develop models of the Chromate corrosion
inhibitive properties, coating composition and structure both as a
function of substrate composition, solution and coating aging and
underlying intermetallic composition. SIMS ( static and dynamic) as
well as XPS, EXAFS, XANES and FTIR have been used to develop
comprehensive compositional and structural data.
Mechanisms of Radionuclide Hydroxycarboxlic and Interactions for
Decontamination of Metallic Surfaces
DOE 9/15/98-9/14/01
In this program surface and electrochemical analyses are used to
develop a model of understanding of the use of carboxylic acids on
the chelation of U contamination bound to steel corrosion products.
The research also investigates the effectiveness of cleaning the
contaminated and corroded steel surfaces with citric acid.
Mechanisms of Military Coatings Degradation Strategic Environmental
Research and Development Program (SERDP)
DoD/DOE/EPA 1/1/99
In this program surface analysis is used to determine the chemical
mechanism of degradation of military CARC coatings/paint composite
system. The research will also develop of Life Cycle Analysis
models to predict service life. Electrochemistry compliments the
surface analytical tools used to study these systems.
Corrosion Protective Coatings for Depleted Uranium Penetrator
Systems US Army Research Office 9/26/01 - 9/25/04
The research is aims to develop environmentally benign corrosion
resistant coating system for depleted uranium munitions. Protective
coatings formed on weapons using DU could prevent leaching of DU
into the environment as well as prevent localized corrosion in
seawater spray during transportation.
Synergistic Effects of Multiple Environments on Composite Degradation
NSF 8/15/02 - 8/14/05
Effect of various external factors such as temperature, humidity,
mechanical stress, etc on the degradation of composites is studied.
The project aims to develop life cycle analysis models for the
conjoint effect of all factors.
Teaching Activities:
Undergraduate and Graduate Courses Taught at Stony Brook:
| ESG/ESM 332 | | Introduction to Materials Science |
| ESG/ESM 339 | | Thin Film Processing of Advanced Materials |
| ESM/CHE 347 | | Physical Chemistry of Interfaces |
| ESM 309 | | Thermodynamics of Solids |
| ESM 509 | | Thermodynamics of Solids |
| ESM 307 | | Physical Metallurgy |
| ESM 696 | | Special Problems:Lectures in Corrosion Science |
| ESM 696 | | Special Problems: Lectures in Applied Surface Science |
Contributions to Curriculum Development:
ESG/ESM 339 This course was developed to meet the demand by ABET
for extra design credit for materials processing. It also meets the
need to provide students for the first time both training in vacuum
engineering and surface analysis as well as semiconductor
processing. This course is a required course in Engineering
Science.
ESM 307 was developed to provide students with a lecture and
laboratory training in physical metallurgy theory and practice.
ESM/CHE 347 In this course students from Engineering Science and
Engineering Chemistry were introduced to the science and technology
of electrified interfaces and the thermodynamic and kinetic
description of chemical processes occurring across natural and
engineering interfaces.
ESM 696 Special Problems:Lectures in Corrosion Science and ESM 696
Special Problems: Lectures in Applied Surface Science were lecture
courses designed to provide first year graduate students with solid
theoretical grounding and an introduction to the literature in
these two subjects which form the basis of Prof. Clayton's
research.
Publications:
PhD Thesis:
The Application of XPS to The Study of the Passive Layers Formed on
Metals in Aqueous Conditions. C.R. Clayton, Ph.D. Thesis,
University of Surrey, (1976). (Prof. James E. Castle Advisor)
Chapters in Books:
Passivity of Austenitic Stainless Steels Chapter VI, by Clive
R.Clayton and Ingemar Olefjord in Corrosion Mechanisms Eds., P.
Marcus and J. Oudar, Marcel Dekker, New York (1995)
Applications of Surface Alloying Techniques, Chapter XII, J.K.
Hirvonen and C.R. Clayton, in Surface Modification and Alloying,
Eds. J.M. Poate, G. Foti and D.C. Jacobson, NATO Conf. Series,
Plenum, NY (1983).
Chemical Effects of Ion Implantation: Oxidation, Corrosion and
Catalysis, Chapter X. C.R. Clayton in Surface Alloying By Ion,
Electron and Laser Beams: ASM Special Seminar Series, Eds. L.E.
Rhen, S.T. Picraux and H. Weidersich, ASM Metals Park, Ohio (1987).
Gary P. Halada and Clive R. Clayton, The Intersection of Design,
Manufacturing and Surface Engineering, Chapter in Handbook of
Environmental Degradation of Materials, Myer Kutz, editor, John
Wiley and Sons, New York, (2005)
Clive R. Clayton, Gary P. Halada and Pelagia Gouma, "Microscopy and
Microspectroscopy of Aluminum and Ferrous Alloys and Their Surface
Treatments", in Analytical and Mechanical Characterization of
Aluminum and its Alloys, George E. Totten and D. Scott MacKenzie,
editors, Marcel Dekker, Inc., New York, (2005)
Research Papers in Reviewed Journals:
- The Use of X-Ray Photoelectron Spectroscopy in the Analysis of
Passive Layers on Stainless Steel with J.E.Castle Corrosion
Science, 7, 1 (l977).
- Fatigue Life Enhancement by Ion Implantation-I with W.W. Hu, H.
Herman and J.K. Hirvonen, Scripta Met. 12, 697, (1978).
- Application of Ion Implantation for the Improvement of Localized
Corrosion Resistance of M50 Bearing Steel with Y.F. Wang, G.K.
Hubler and W. Lucke, Thin Solid Films, 63, 11, (1979).
- Cavitation Behaviour of Active Thermal Sprayed Coatings with J.
Vargas, M. Dorfman and H. Herman, Thin Solid Films, 64, 351,
(1979).
- Interpretations of the Electrochemical Behaviour of Nickel-
Implanted Type 430 Stainless Steel Using XPS and TEM with S.B.
Agarwal, Y.F. Wang, H. Herman and J.K. Hirvonen, Thin Solid Films,
63, 19, (1979).
- Modification of the Mechanical Properties Through Ion
Implantation with H. Herman, J.K. Hirvonen, R. Kant and R.K.
MacCrone, Thin Solid Films 73, 189, (1980).
- Cavitation-Erosion of Ion Implanted 1018 Steel with W.W. Hu and
J.K. Hirvonen, Mat. Sci. and Eng., 45, 263, (1980).
- Fatigue Life Enchancement by Ion Implantation-II with W.W. Hu,
H. Herman, J. K. Hirvonen and R. Kant, Finomechanica Mikrolechnika
(in Hungarian) (1980) and Radiation Effects, 49, 71, (1980).
- Microstructural Characterization of Plasma-Sprayed Ferrous
Alloys with H. Bhat, H. Herman, J. Jach and R. Zatorski, Thin Solid
Films, 72, 153, (1980).
- Mechanical Properties Modification by Ion Implantation with H.
Herman, W.W. Hu, J.K. Hirvonen, R. Kant and R.K. MacCrone, Thin
Solid Films, 73, 189 (1980).
- Modification of Metallic Corrosion by Ion Implantation, Nucl.
Instr. and Methods, 182/183, 865, (1981).
- Electrochemical and AES Studies of the Fe-Cr Surface Alloys
Formed on AISI 52100 by Ion Beam Mixing, with W.K. Chan, R.G.
Allas, C.R. Gossett and J.K. Hirvonen, Nuclear Instruments and
Methods 209/210, 857, (1983).
- Modification of the Corrosion Behaviour of Engineering Alloys
by Ion Implantation, with Y.F. Wang, IEEE Transactions on Nuclear
Science, Vol. NS-30, No. 2, 1752, (1983).
- Surface Enrichment of Nitrogen During Passivation of a Highly
Resistant Stainless Steel, with Y. Lu, R. Bandy and R.C. Newman, J.
Electrochemical Society, 130, 1774, (1983).
- The Electrochemical Behaviour of Niobium Low Pressure Plasma
Sprayed Coatings in Hydrochloric Acid, with J.D. Reardon, F.N.
Longo and K.G.K. Doss, Thin Solid Films, 108, 459, (1983).
- The Mechanical and Chemical Properties of Tantalum Implanted
Steel, with G.K. Hubler, I.L. Singer J. Mat. Sci. & Eng., 69
(1985), p. 203.
- Evidence for a Bipolar Mechanism of Passivity in Mo bearing
Stainless Steel, with Y.C. Lu Journal of the Electrochemical
Society, 132, p. 2517.
- On the Role of Cr in the Passivity of Stainless Steel, with
A.R. Brooks, K. Doss and Y.C. Lu, J. of Electrochemical Society
133, 12, 2459 (1986).
- A Bipolar Model of the Passivity of Stainless Steel: The Role
of Mo Addition with Y.C. Lu, J. of Electrochemical Society 133, 12,
2465 (1986).
- Biomembranes as Models of Polymer Surfaces IV: ESCA Analyses of
a Phosphorylcholine Surface Covalently Bound to Hydroxylated
Substrates, with James A. Hayward, Aziz, A. Durrani, Yucheng Lu,
and Dennis Chapman, Biomaterials, p. 7, 252 (l986).
- Evidence of Chemical Passivity of an Amorphous Ni-P Alloy, with
R.B. Diegle, N.R. Sorensen and Y.C. Lu, J. Electrochem. Soc., 134,
1. 138 (1987).
- XPS Investigation into the Passivity of an Amorphous Ni-20P
Alloy, with R.B. Diegle, N.R. Sorensen and Y.C. Lu, J. Electrochem.
Soc.,6 135, 5, 1085 (1988).
- Variable Angle XPS and Its Application in Studies of The
Passive Films Formed on Stainless Steels, with Y.C. Lu J Chin. Soc.
Corr. Prot., 8, 29 (1988).
- Effects of Polyacrylic Acid Primers on Adhesion and Durability
of FPL-Etched Aluminum/Polyurethane Bonding, with T. Sugama, L.E.
Kukacka and H.C. Hua, J. of Adhesion Science 1, 4,(1987), p.265.
- Evidence of Photoreduction in Thermal Oxides Formed on
Chromium, with G. P. Halada, D. Lindsley, Materials Science and
Engineering A. p.103 L5,(1988).
- Evaluation and Correction of the Effect of Surface Roughness on
Thin Film Thickness Measurements Using V.A.X.P.S., with Y.L. Yan
Appl.Surface Science, p.37,395,(1989).
- A Bipolar Model of the Passivity of Stainless Steel: Part III
The Mechanism of MoO4 -Formation and Incorporation, with and Y.C.
Lu, Corrosion Science, 29, 7, 881, (1989).
- An XPS Study of the Passive and Transpassive Behavior of
Molybdenum in Deaerated O.1 M HCl, Y.C. Lu Corrosion Science, 29,
8, 927 (1989).
- Electrochemical and XPS Evidence of the Aqueous Formation of
Mo2O5, with Y. C. Lu, Surface and Interface Analysis. 14, 66
(1989).
- A Bipolar Model of the Passivity of Stainless Steel: Part II
Influence of Solution Borne Molybdate Ions, with Y.C. Lu and
A.Brooks. Corrosion Science. p.29,7,863,(1989).
- Surface Composition of Stainless Steel During Active
Dissolution and Passivation, with I.Olefjord ISIJ Internat 31, 2,
136 (1991).
- Photoreduction of Hexavalent Chromium During XPS Analysis of
Electrochemical and Thermal Films, with G.P.Halada J.Electrochem
Soc. 138, 10 (1991).
- The Role of P in the Inhibition of an Amorphous Co-20P Alloy in
Acidic Electrolytes, with M.A.Helfand, R.B.Diegle and N.R.Sorensen
Submitted to J.Electrochem. Soc. 139, 8 (1991).
- The Application of XPS to The Study of Microbiologically
Induced Corrosion, J.R.Kearns, C.R.Clayton, G.P.Halada, J.B.Gillow
and A.J.Francis, Materials Performance, 31, No. 10 48 (1991).
- Synergism of Alloying Elements and Pitting Corrosion Resistance
of Stainless Steels with Y.C.Lu, M.B.Ives, UMIST 20th Anniversary
Symposium 1992 in Corros Sci., 35, 1, 89 (1991).
- A Comparison of Mo-N and W-N Synergism during Passivation of
Stainless Steel through X-Ray Photoelectron Spectroscopy and
Electrochemical Analysis with G.P.Halada J of Vac Sci and Tech A 11
4, 2342 (1991).
- On the Question of Nitrate Formation by N-bearing Austenitic
Stainless Steel with D.Kim and M.Oversluizen Materials Science and
Engineering A 186 163, (1991).
- XPS and XANES Studies of Uranium Reduction by Chlostridium sp.
with A.J. Francis, C.J.Dodge, F.Lu, G.Halada and Env. Sci and
Tech.Vol 28, 4, 636 (1991).
- An XPS Study of the Passive Film Formed on Mo and MoSi2 in 4M
HCl with G.P.Halada, H.Herman, S.Sampath and R.Tiwari J.
Electrochemical Soc. 142, 1, 74 (1995).
- Passivity of High Nitrogen Stainless Steels: The Formation and
Role of Prepassive Ultra-Thin Films with G.P.Halada and J.R.Kearns
Proc. of US-Japan Seminar Timberline Lodge, Mount Hood, Oregon 7-9
June 1994 Eds., R. Latanision and K.Hashimoto,. Materials Science
and Engineering A 198 135 (1995).
- Metal Ion and Exopolymer Interaction: A Surface Analytical
Study, G.Chen, S.V.Kagewade, G.E.French, T.E.Ford , R.Mitchell and
C.R.Clayton Corrosion No12 891 (1995).
- Surface Analytical Study of the Influence of Nitrogen on The
Electrochemical Passivation of High Ni Stainless Steels and Thin Mo-
Ni Films G.P.Halada, D.Kim and C.R.Clayton Corrosion 52, No 1, 36
(1995).
- Investigations of The Uptake of Transuranic Radionuclides by
Humic Acid and Fulvic Acids Chemically Immobilized on Silica Gel
and Their Competitive Release by Complexing Agents R.A.Bulman, G.
Szabo, R.F.Clayton and C.R.Clayton Waste Management 17, No4 (1996).
- Influence of Sulphate Reducing Bacteria on the Passivity of
type 304 Stainless Steel G.Chen and C.R.Clayton J.Electrochemical
Society 144, 9 3140 (1997).
- Interaction of Sulphate-Reducing Bacteria with Molybdenum
Dissolved from Sputter- deposited Molybdenum Thin Films and Pure
Molybdenum Powder G.Chen, T.E.Ford and C.R.Clayton J. Colloidal and
Interface Science 204, 237 (1998).
- The Influence of Sulphate Reducing Bacteria on the Passivity of
type 317L Austenitic Stainless Steel G.Chen and C.R.Clayton
J.Electrochemical Society 145, 6 1914 (1998).
- Influence of Corrosion on the Fatigue Properties of Al 7075-T6
M.L.Du, F.P.Chiang, S.V.Kagwade and C.R.Clayton J.of Testing and
Evaluation 26, No3 92 (1998).
- XPS Study of Mo(V) Commonly Observed in Passive Films Formed on
Stainless Steels with D.Kim, and S.V.Kagwade Surface and Interface
and Analysis 26, 155 (1998).
- Damage of Al 2024 Alloy Due to Sequential Exposure to Fatigue,
Corrosion Fatigue. M.L.Du, F.P.Chiang, S.V.Kagwade and C.R.Clayton
International Journal of Fatigue Vol20, No10 743 (1998).
- X-ray Photoelectron Spectroscopy Analysis of Mo Metal Surface
Exposed to Sulphate-Reducing Bacteria G.Chen and C.R. Clayton
Surface and Interface Analysis 27, 230 (1999).
- On the Causes and Prevention of Photochemical Reduction of
Hexavalent Chromium During X-ray Photoelectron Spectroscopy
S.V.Kagwade, C.R.Clayton and G.P.Halada Critical Reviews in Surface
Chemistry (accepted for publication).
- The influence of acetone degreasing on the corrosion behavior
of AA2024-T3, Kagwade SV, Clayton CR, Chidambaram D, et al.,
Journal of the Electrochemical Society; 147, 4125 (2000).
- S. V. Kagwade, C. R Clayton, D. Chidambaram, F. P. Chiang and
Y. Lu, The influence of acetone degreasing on the corrosion
behavior of AA2024-T3, Journal of the Electrochemical Society, 147
(11), 4125-4130 (2000).
- D. Chidambaram, G. P. Halada and C. R. Clayton, Development of
a technique to prevent radiation damage of chromate conversion
coatings during X-ray photoelectron spectroscopic analysis, Applied
Surface Science, 181 (3-4), 183-195 (2001).
- D. Chidambaram and G. P. Halada, Infrared microspectroscopic
studies on the pitting of AA2024-T3 induced by acetone degreasing,
Surface and Interface Analysis, 31 (11), 1056-1059 (2001).
- D. Chidambaram, G. P. Halada and C. R. Clayton, On the
electrochemical behavior of dichromate and molybdate treated
intermetallic particles present in AA2024-T3, in Corrosion and
Corrosion Prevention of Low Density Metals and Alloys, 198th
Meeting of the Electrochemical Society, B.A. Shaw and R.G.
Buchheit, Eds., The Electrochemical Society, Pennington, NJ, PV2000-
23, 101-110 (2001).
- S. V. Kagwade, C. R Clayton, D. Chidambaram, and G. P. Halada,
Photochemical breakdown of acetone on copper, Electrochimica Acta,
46 (15), 2337-2342 (2001).
- Development of a technique to prevent radiation damage of
chromate conversion coatings during X-ray photoelectron
spectroscopic analysis. Chidambaram D, Halada GP, Clayton CR.
Applied Surface Science;181(3-4):283-95. (2001).
- The application of laboratory and synchrotron-based
spectroscopic techniques to the study of passive films and
corrosion protective layers. Clayton CR, Halada GP. Zairyo to
Kankyo; 50 (8):364-71 (2001).
- Photochemical breakdown of acetone on copper. Kagwade SV,
Clayton CR, Chidambaram D, Halada GP. Electrochimica Acta 46 (15):
2337-42 (2001).
- Causes and prevention of photochemical reduction of hexavalent
chromium during x-ray photoelectron spectroscopy, Kagwade SV,
Clayton CR, Halada GP. Surface and Interface Analysis; 31 (6): 442-
7 (2001).
- D. Chidambaram, C. R. Clayton, and G. P. Halada, Effect of
Surface Pretreatments on Chromate Conversion Coatings, in State-of-
the-Art Application of Surface and Interface Analysis Methods to
Environmental Material Interactions, 199th Meeting of the
Electrochemical Society, D. R. Baer, C. R. Clayton, G. P. Halada
and G. D. Davis, Eds., The Electrochemical Society, Pennington,
NJ., PV2001-5, 282-291 (2002).
- D. Chidambaram, C. R. Clayton, and G. P. Halada, Studies on
the Repassivation Behavior of Aluminum Exposed to Dichromate
Solution, in State-of-the-Art Application of Surface and Interface
Analysis Methods to Environmental Material Interactions: 199th
Meeting of the Electrochemical Society, D. R. Baer, C. R. Clayton,
G. P. Halada and G. D. Davis, Eds., The Electrochemical Society,
Pennington, NJ., PV2001-5, 240-249 (2002).
- The Application of synchrotron-based spectroscopic techniques
to the study of chromate conversion coatings. Vasquez MJ, Halada
GP, Clayton CR. Electrochimica Acta; 47 (19):3105-15 (2002).
- On the nature of the chromate conversion coating formed on
intermetallic constituents of AA2024-T3., Vasquez MJ, Halada GP,
Clayton CR, Longtin JP. Surface and Interface Analysis;33 (7): 607-
16 (2002).
- Spatially resolved microchemical analysis of chromate-
conversion-coated aluminum alloy AA2024-T3. Vasquez MJ, Kearns JR,
Halada GP, Clayton CR. Surface and Interface Analysis; 33(10/11):
796-806 (2002).
- D. Demaree, C. R. Clayton, D. Chidambaram, D. F. Roeper, and
G. P. Halada, Corrosion Protective Coatings for Depleted Uranium,
Proceedings of the Tri-Service Corrosion Conference (2003).
- D. Chidambaram, C. R. Clayton, and G. P. Halada, A Duplex
Mechanism Based Model for the Interaction between Chromate Ions and
the Hydrated Oxide film on Aluminum Alloys, Journal of The
Electrochemical Society, 150, 5, B224-B237 (2003).
- D. Chidambaram, M. J. Vasquez, G. P. Halada, and C. R.
Clayton, Studies on the repassivation behavior of aluminum and
aluminum alloy exposed to chromate solutions, Surface Interface
Analysis, 35, 226-231 (2003).
- C. R. Clayton, D. Chidambaram, D. F. Roeper, and G. P. Halada,
Towards the development of environmentally-friendly corrosion
resistant coatings for depleted uranium-0.75 wt% titanium alloy, in
Critical Factors in Localized Corrosion IV: A Symposium in Honor of
the 65th Birthday of Hans Bohni; 202nd Meeting of The
Electrochemical Society-, S. Virtanen, P. Schmuki and G. S.
Frankel, Eds., The Electrochemical Society, Pennington, NJ., PV2002-
24, 572 (2003).
- Surface Pretreatments of Aluminum Alloy AA2024-T3 and Formation
of Chromate Conversion Coatings 1: Composition and Electrochemical
Behavior of the Oxide Film. Chidambaram D, Clayton CR, Halada GP,
Kendig MW. Journal of the Electrochemical Society; Under Review.
(2003).
- Surface Pretreatments of Aluminum Alloy AA2024-T3 and Formation
of Chromate Conversion Coatings 2: Composition and Electrochemical
Behavior of the Chromate Conversion Coating. Chidambaram D, Clayton
CR, Kendig MW, Halada GP. Journal of the Electrochemical Society;
Under Review (2003).
- Spectroscopic Elucidation of the Repassivation of Active Sites
on Aluminum by Chromate Conversion Coating. Chidambaram D, Halada
GP, Clayton CR. Electrochemical and Solid State Letters; Revised
(2003).
- A Duplex Mechanism Based Model for the Interaction between
Chromate Ions and the Hydrated Oxide film on Aluminum Alloys.
Chidambaram D, Clayton CR, Halada GP. Journal of the
Electrochemical Society;150 (5): B224-B37 (2003).
- Studies on the repassivation behavior of aluminum and aluminum
alloy exposed to chromate solutions. Chidambaram D, Vasquez MJ,
Halada GP, Clayton CR. Surface and Interface Analysis; 35 (2): 226-
30 (2003).
- Evaluation of the Electrochemical Behavior of HVOF-Sprayed
Alloy Coatings. Chidambaram D, Clayton CR, Dorfman MR. Surface and
Coatings Technology; 176 (3): 307-17 (2004).
- Fabrication of Nanostructed Al2CuMg Thin Film by Femtosecond
Pulsed Laser Ablation. Vasquez MJ, Halada GP, Clayton CR, Gouma PI.
Thin Solid Films;In Press. (2004).
- D. Chidambaram, C. R. Clayton, M. W. Kendig and G. P. Halada,
Surface Pretreatments of Aluminum Alloy AA2024-T3 and Formation of
Chromate Conversion Coatings 2: Composition and Electrochemical
Behavior of the Chromate Conversion Coating. Journal of The
Electrochemical Society, 151, 11, B613 (2004).
- D. Chidambaram, C. R. Clayton, G. P. Halada and M. W. Kendig,
Surface Pretreatments of Aluminum Alloy AA2024-T3 and Formation of
Chromate Conversion Coatings 1: Composition and Electrochemical
Behavior of the Oxide Film, Journal of The Electrochemical Society,
151, 11, B605 (2004).
- D. Chidambaram and C. R. Clayton, The Role of Fluoride
Compounds in the Formation of Chromate Conversion Coatings on
Aluminum Alloys, in Corrosion and Corrosion Prevention of Low
Density Metals and Alloys - II, 204th Meeting of the
Electrochemical Society, R.G. Bucheit, R.G. Kelly, B.A. Shaw, N.
Missert, Eds., The Electrochemical Society, Pennington, NJ, PV2003-
23, 203 (2004).
- D. Chidambaram, G. P. Halada, and C. R. Clayton, Spectroscopic
Elucidation of the Repassivation of Active Sites on Aluminum by
Chromate Conversion Coating, Solid State and Electrochemical
Letters, 7, 9, B31 (2004).
- D. Chidambaram, G. P. Halada, and C. R. Clayton, Synchrotron
Radiation Based Grazing Angle Infrared Spectroscopy of Chromate
Conversion Coatings Formed on Aluminum Alloys, Journal of The
Electrochemical Society, 151, 3, B160 (2004).
- D. Chidambaram, C. R. Clayton, and G. P. Halada, Interactions
of the Components of Chromate Conversion Coating with the
Constituents of Aluminum Alloy AA2024-T3, Journal of The
Electrochemical Society, 151, 3, B151 (2004).
- D. Chidambaram, C. R. Clayton, and M. Dorfman, Evaluation of
the Electrochemical Behavior of HVOF-Sprayed Alloy Coatings,
Surface & Coatings Technology, 176, 3, 307 (2004).
- D. F. Roeper, D. Chidambaram, C. R. Clayton, and G. P. Halada,
Development of an Environmentally-Friendly Protective Coating for
the Depleted Uranium-0.75 Wt% Titanium Alloy. Part II: Coating
Formation and Evaluation, Electrochimica Acta, 51, 3, 545 (2005).
- D. F. Roeper, D. Chidambaram, C. R. Clayton, and G. P. Halada,
Development of an Environmentally-Friendly Protective Coating for
the Depleted Uranium-0.75 Wt% Titanium Alloy. Part I: Surface
Morphology And Electrochemistry, Electrochimica Acta, 50, 18, 3622
(2005).
- D. Chidambaram, C. R. Clayton, and M. Dorfman, Evaluation of
the Electrochemical Behavior of HVOF-Sprayed Alloy Coatings – II,
Surface & Coatings Technology, 192, 2, 278 (2005).
- Lionel T. Keene, Gary P. Halada and Clive R. Clayton, Failure
of Navy Coatings Systems 1: Chemical Depth Profiling of
Artificially and Naturally Weathered High-Solids Aliphatic
Poly(ester-urethane) Military Coating Systems, Progress in Organic
Coatings, vol. 52, pp. 173-186 (2005) .
- Lionel T. Keene, M. Jaime Vasquez, Clive R. Clayton and Gary P.
Halada, Failure of Navy Coatings Systems 2: Failure Pathways of
Artificially Weathered Navy Coating Systems Applied to Chromate
Conversion Coated AA2024-T3 Substrates, Progress in Organic
Coatings, vol. 52, pp. 187-195 (2005).
- D. F. Roeper, D. Chidambaram, C. R. Clayton, and G. P. Halada,
Development of an Environmentally-Friendly Protective Coating for
the Depleted Uranium-0.75 Wt% Titanium Alloy. Part IV: Vibrational
Spectroscopy of the Coating, Electrochimica Acta, 51, 23, 4815
(2006).
- D. F. Roeper, D. Chidambaram, C. R. Clayton, G. P. Halada and
J. D. Demaree, Development of an Environmentally-Friendly
Protective Coating for the Depleted Uranium-0.75 Wt% Titanium
Alloy. Part III: Chemical Analysis of the Coating, Electrochimica
Acta, 51, 19, 3895 (2006).
- D. Chidambaram, C. R. Clayton and G. P. Halada, The Role of
Hexafluorozirconate in the Formation of Chromate Conversion
Coatings on Aluminum Alloys, Electrochimica Acta, 51, 14, 2862
(2006).
- D. F. Roeper, D. Chidambaram, C. R. Clayton, and G. P. Halada,
Development of an Environmentally-Friendly Protective Coating for
the Depleted Uranium-0.75 wt.% Titanium Alloy. Part V:
Electrochemical Impedance Spectroscopy of the Coating,
Electrochimica Acta, 53, 5, 2130 (2008).
- D. Chidambaram, G. P. Halada, and C. R. Clayton, On the
Photochemical Degradation of Hexavalent Chromium During XPS
Analysis, Journal of Electron Spectroscopy and Related Phenomena,
Submitted. Invited Review.
Edited Articles:
- D. Chidambaram, C.R. Clayton and G.P. Halada, SIRMS Studies on
the Repassivation of Aluminum Exposed to Dichromate Solution,
National Synchrotron Light Source Annual Report 2000, Mary Anne
Corwin (Managing Editor), BNL, Brookhaven Science Associates, Inc.
(2000).
- D. Chidambaram, C.R. Clayton, G.P. Halada, Effect of Surface
Pretreatments On Chromate Conversion Coatings, National
Synchrotron Light Source Annual Report 2001, Mary Anne Corwin
(Managing Editor), BNL, Brookhaven Science Associates, Inc. (2001).
- D. Chidambaram, C. R. Clayton, G. P. Halada, On the Formation
of Cr(VI)-rich Chromate Conversion Coatings in Mechanically Damaged
Areas on AA2024-T3, National Synchrotron Light Source Annual
Report 2002, Mary Anne Corwin (Managing Editor), BNL, Brookhaven
Science Associates, Inc. (2002).
- D Chidambaram, G.P. Halada and C.R. Clayton, Grazing Angle
Infrared Spectroscopy of Chromate Conversion Coatings National
Synchrotron Light Source Annual Report 2002, Mary Anne Corwin
(Managing Editor), BNL, Brookhaven Science Associates, Inc. (2002).
Research Papers in Reviewed Proceedings: (Not Including Extended
Abstracts)
- A High Temperature Transition in the Mechanism of Film Formation
on Stainless Steel in Water with J.E. Castle in Passivity of
Metals, Eds. J. Kruger and, R.P. Frankenthal, Electrochem. Soc.,
Princeton, NJ, p.714, (1978).
- Surface Related Mechanical Properties of Nitrogen-Implanted 1018
Steel with W.W.Hu, H.Herman, J.Kozubowski, R.A.Kant, J.K.Hirvonen
and R.K.MacCrone in Ion Implantation Metallurgy, Eds: C.M.Preece
and J.K.Hirvonen, AIME, p92 (1980).
- Modification of the Corrosion Behaviour of 304 Stainless Steel
by Phosphorous Implantation with K.G.K. Doss, H. Herman, S. Prasad,
Y.F. Wang, J.K. Hirvonen and G.K. Hubler in Ion Implantation
Metallurgy, Ed. C.M. Preece and J.K. Hirvonen, TMS- AIME, New York
(1980).
- The Effects of Post-Treatment Upon the Cavitation Behaviour of
Al-Sprayed Coatings in 3.5 wt% Sodium Chloride Solution with M.R.
Dorfman and H. Herman, Proc. of the 9th Int. Thermal Spraying
Conf., The Hague, May p249 (1980).
- Mossbauer Spectroscopy of Plasma-Sprayer Ferrous Alloys with H.
Bhat, H. Herman, J. Jach and R. Zatorski, Proc. of the 9th Int.
Thermal Spraying Conf., The Hague, p287 May (1980).
- Cavitation-Induced Corrosion of Marine Metallic Coatings with M.
Dorfman and H. Herman, Proc. Marine Technology Society, Washington,
DC, Oct. (1980).
- Application of Ion Implantation for the Improvment of Localized
Corrosion Resistance of M50 Steel Bearings with G.K. Hubler, J.K.
Hirvonen, I. Singer, C.R. Grosset, Y.F. Wang and J. Budnik, Naval
Research Lab., Memorandum Report 4481, (1980).
- Corrosion
Resistant AISI 52100 Bearing Surfaces by Ion Implantation with G.K.
Hubler and K.W. Chan, Naval Research Laboratory Memorandum Report,
4527, June, (1981).
- Characterization and Properties of Laser Quenched Aluminum
Bronzes with C.W. Draper, J.M. Vanderburg and C.M. Preece, in
Rapidly Solidified Amorphous and Crystalline Alloys, Eds. B.L.H.
Kear, B.C. Giessen and M. Cohen, Elsevier (1982), p.529.
- The Electrochemical Corrosion Behaviour of Laser Quenched Fe-
Aluminum Bronze with J. Javadpour and C.W. Draper, in Corrosion of
Metals Processed by Directed Energy Beams, Eds. C.R. Clayton and
C.M. Preece, TMS-AIME, New York (1982), p.135.
- Electrochemical and AES Studies of Fe-Cr Surface Alloys formed
on AISI 52100 Steel by High-Dose Ion Implantation with K.W. Chan
and J. K. Hirvonen, in Corrosion of Metals Processed by Directed
Energy Beams, Eds. C. R. Clayton and C. M. Preece, TSM- AIME, New
York (l982), p. 91.
- RHEED, AES and XPS Studies of the Passive Films Formed on Ion
Implanted Stainless Steel, with K.G.K. Doss, Y.F. Wang, J.B. Warren
and G.K. Hubler, in Ion Implantation into Metals, Eds: V. Ashworth,
W.A. Grant and R.P.M. Procter, Pergamon, Oxford, (1982), p. 67.
- Structure and Stability of the Anodically Formed Films on 304
Stainless Steel in 0.5 M H2SO4, with K.G.K. Doss and J.B. Warren in
Passivity of Metals and Semiconductors, Ed. M. Froment, Elsevier,
New York, (1983), p.305.
- An Electrochemical Study of Amorphous Ion Implanted Stainless
Steel, with Y.F. Wang and G.K. Hubler, Ibid., p.585.
- Modification of the Localized Corrosion Behaviour of AISI 52100
Steel by Ion Implantation, with W.K. Chan, J.K. Hirvonen, G.K.
Hubler and J.R. Reed in Fundamental Aspects of Corrosion Protection
by Surface Modification, Eds: E. McCafferty, C.R. Clayton and J.
Oudar, Electrochemical Society, Princeton, NJ. (1984), p.17.
- Modification of the Passivity of 316 Stainless Steel by P and B
Implantation, with Y.F. Wang and G.K. Hubler, Ibid., p.32.
- Mechanism of the Passivation of Stainless Steels Containing
High Concentrations of Nitrogen, with R.C. Newman, Y. Lu, R. Bandy
to be published in Proc. of Int. Congress on the Metallic
Corrosion, Toronto, June 1984, Vol. 3, p. 394.
- Structural Transitions in Passive Films Formed on Stainless
Steel, with K. Doss, A.R. Brooks Ibid., Vol.1, p. 138.
- Ion Mixing of Cr Layers on Steel: Effect of Impurities During
Ion Mixing, K. Grabowski, with R.J. Colton, W.K. Chan Workshop on
Ion Mixing and Surface Layer Alloying, Eds. M.A. Nicolet and S.T.
Picraux, Noyes Pub. Park Ridge N.J.(1984), p108
- High Dose Ion Implantation and Corrosion Behaviour of Ferrous
Metals, with B.D. Sartwell, N.S. Wheeler, G.K. Hubler, E.
McCafferty ibid p128
- The Modification of Metallic Corrosion by Ion Implantation:
Engineering Applications and Fundamental Studies, with Proceedings
of the Ion Implantation for Army Needs Workshop, AMMRC-MS-84-1,
June 1984, p. 127.
- The Influence of Incorporated Anions and Bound Water on the
Formation and Stability of Anodic Films Formed on Stainless Steel,
with A.R. Brooks, K. Doss and Y.C.Lu, in Equilibrium Diagrams and
Localized Corrosion, Eds. R.P. Frankenthal and J. Kruger,
Electrochem. Soc. (1984), p.369.
- Role of Nitrogen in Improving Resistance to Localized Corrosion
in Austenitic Alloys, R. Bandy, with Y.C. Lu, R.C. Newman Ibid., p.
471.
- The Influence of Nitrogen on the Passivity of 18-8 (0.24%N)
Stainless Steels, with L. Rosenzweig, M. Oversluizen and Y.C. Lu,
in Surfaces, Inhibition and Passivation, Ed. E. McCafferty and R.J.
Brodd, Electrochemical Society, Pennington, NJ (1986).
- An XPS Study of the Anodic Inhibition of An Amorphous Cr-20P
Alloy. Corrosion Electrochemistry and Catalysis of Metallic Glasses
with M.A. Helfand, R.B. Diegle and N.R.Sorensen. Eds. R.B. Diegle
and K. Hashimoto, Electrochemical Society, Pennington, N.J. (1988),
p. 104.
- Anodic Behaviour of Ni-P and Ni-Cr-P Metallic Glasses.
Corrosion Electrochemistry and Catalysis of Metallic Glasses. with
R.B. Diegle, N.R. Sorensen and M.A. Helfand. Eds. R.B. Diegle and
K. Hashimoto, Electrochemical Society, Pennington, N.J. (1988), p.
80.
- An XPS Study of the Passivity of Amorphous Ni-20P-XCr Alloys.
Corrosion Electrochemistry and Catalysis of Metallic Glasses.with
M.A. Helfand, R.B. Diegle and N.R. Sorensen. Eds. R.B. Diegle and
K. Hashimoto. Electrochemical Society, Pennington, N.J. (1988), p.
134.
- Evidence of Anodic Segregation of Nitrogen in High Nitrogen
Stainless Steel and its Influence on Passivity with and K.G.
Martin, Proceedings of Int Conf. on High Nitrogen Steel, Lille May
1988. Eds. A. Hendry and J. Foche. HNS 88 London, p. 256 (1989).
- Applications of Directed Energy Beams in Fundamental and
Applied Studies of the Aqueous Corrosion of Metals in Proc. of
Evironmental Degredation of Ion and Laser Beam Treated Surfaces,
Eds. G.S. Was and K.S. Grabowski TMS. Warrendale, PA (1989), p.33.
- he Effects of Mo Alloying and Aqueous Molybdate on Passive
Film Chemistry of Stainless Steels in Chloride Solutions, with R.E.
Wistrom, Y.C. Lu and D.J. Duquette. Proc. of Int. Symp on Corrosion
Science and Engineering in Honour of M. Pourbaix's 85th Birthday.
Brussels, Belgium, March 12-15 1989. Eds., R.A.Rapp, N.A.Gokcen and
A. Pourbaix. CEBELCOR VOL 1 pp407-417, (1989).
- An XPS and Electrochemical Study of the Influence of Molybdenum
and Nitrogen on the Passivity of Austenitic Stainless Steel,with
R.D. Willenbruch M.Oversluizen, D. Kim and Y.C. Lu, Proc. 6th Int.
Symp. on Passivity, Sapporo, Hokkaido, Japan, Sept.24-28 (1989).
- Polyelectrolyte-Diffused Zinc Phosphate Conversion Coatings and
Polyacid Coupling Primers for Corrosion Protection of Steel and
Aluminum, and Alkali Catalyzed Hydrolysis of Polymide-Based
Materials BNL Report 43186 (1989).
- Underestimation by XPS of Hexavalent Chromium Species
Incorporated into Corrosion Product Layers, with G.P.Halada in
Application of Surface Analysis Methods to Environmental/Material
Interactions, Eds.D.R.Baer, C.R.Clayton and G.D.Davis,
Electrochemical Society, Pennington, NJ (1991), p99
- XANES and XPS of the Reduction of Ammonium Paramolybdate with
G.P.Halada, H.S.Isaacs and A.J.Davenport in X-ray Methods in
Corrosion and Interfacial Electrochemistry Eds. A.Davenport and
J.G.GordenII Electrochem. Soc. Pennington NJ (1991), p 337
- Application of XPS to the Study of Microbial Influenced
Corrosion with G.P.Halada,C.Dodge, J.Gillow and J.R.Kearns NACE
Corrosion 92 Conference Paper # 92178 Houston, Texas (1992).
- Speciation of Uranium After Microbial Action by XANES and XPS
with C.J.Dodge, A.J.Francis, F.Lu, G.P.Halada, S,V,Kagwade in
Mat.Res.Soc.Symp.Proc.Vol307,p89 1993 Applications of Synchrotron
Radiation Techniques to Materials Science Eds., Dale L. Perry, Neal
D. Shinn, Roger L. Stockbauer, Kevin L. D'Amico and Louis J.
Terminello
- Spectroscopic Study of Sulphate Reducing Bacteria-Metal Ion
Interactions related to Microbially Influenced Corrosion with
G.P.Halada, J.R.Kearns, J.Gillow and A.J.Francis in Microbially
Influenced Corrosion Testing ASTM STP 1232 Eds.Brenda Little and
Jeffery R.Kearns ASTM Philadelphia pp 150-165 (1994).
- An XPS Study of the Effects of pH on Ni-P-Cr Metallic Glass-
Passive Film Composition with M.A.Helfand and N.R.Sorensen in
Corrosion, Electrochemistry and Catalysis of Metastable Metals and
Intermetallics Eds., C.R.Clayton and K.Hashimoto Electrochemical
Soc., Pennington NJ (1994), p119.
- The Effect of Surface Nitriding on the Passivation of Mo-Ni
Thin Films with G.P.Halada ibid p157.
40) Corrosion Behaviour of Ion Implanted Magnesium with A.Joshi and
T.W.Rodger ibid p205
- An XPS Investigation into the Passivity of an Amorphous Ni-20P
Alloy II Effect of pH.with M.A.Helfand and N.R.Sorensen ibid p119
- A Surface and Optical Study of the Influence of Stress on the
Corrosion of Aluminum Alloys with S.V.Kagwade, M.L.Du and
F.P.Chiang NACE Corrosion 95 Conf. Paper # 533 Houston, Texas
(1995).
- Metal Ion and Exoploymer Interaction: A Surface Analytical
Study with G. Chen, S.V.Kagewade, G.E.French, T.E.Ford and R.
Mitchell NACE Corrosion 95 Conf. Paper # 219 Houston, Texas (1995).
- Influence of Sulphate-Reducing Bacteria on the Passive Film
Formed on Austenitic Stainless Steel AISI 304 with G.Chen,
R.A.Sadowski, J.R.Kearns, J.B.Gillow and A.J.Francis NACE Corrosion
95 Conf. Paper # 217 Houston, Texas (1995).
- Electrochemical and Surface Analytical Studies of the
Interaction of Nitrogen with Key Alloying Elements in Stainless
Steel with G.P.Halada, D. Kim and J.R.Kearns NACE Corrosion 95
Conf. Paper # 531 Houston, Texas (1995).
- A Surface Analytical Study of the Influence of Nitrogen on the
Electrochemical Passivation of High Ni Stainless Steel and Thin Mo-
Ni Films with G.P.Halada and D. Kim NACE Corrosion 95 Conf. Paper #
536 Houston, Texas (1995).
- X-ray Spectroscopic Studies of Microbial Transformations of
Uranium C.J.Dodge, A.J.Francis and C.R.Clayton in Application of
Synchrotron Radiation Techniques in Industrial, Chemical and
Materials Science Eds., L.J.Terminello, K.L.D' Amico and S.K.Shuh
Plenum Press, NY (1996), p159-168.
- Multipole RF Switch Contact resistance interference: An
Industrial Application of Surface Analysis with A.F.Hmiel, Y.Bauer,
V.Leikus and G.P.Halada in Advanced Coatings Technologies for
Corrosion Protection C.R.Clayton and J.K.Hirvonen in Advanced
Coatings Technologies for Corrosion and Wear Resistant Coatings
Eds., A.R.Srivatsa, C.R.Clayton and J.K.Hirvonen TMS Warrendale PA
(1995), p 211
- Advanced Coatings Technologies for Corrosion Protection
C.R.Clayton and J.K.Hirvonen in Advanced Coatings Technologies for
Corrosion and Wear Resistant Coatings Eds., A.R.Srivatsa,
C.R.Clayton and J.K.Hirvonen TMS Warrendale PA (1995), p 27
50) An XPS Study of the Role of Nitrogen in Oxyanion Formation
During Aqueous Corrosion of Molybdenum and Chromium Nitride,
G.P.Halada, M.E. Monserrat, C.R. Clayton and J.D. Demaree, Advances
in Coatings Technologies for Surface Engineering Eds., C.R.Clayton,
J.K.Hirvonen and A.Srivatsa TMS Warrendale PA (1997), p339
- A Study of the Passivation Mechanism in Highly Corrosion
Resistant "Stainless Steel" Alloy Coatings Formed by Using JVDTM
Process. C.R.Clayton, G.P.Halada, M.E. Monserrat, S.V. Kagwade,
J.Di, T.Tamagawa, A.R. Srivatsa and B.L.Halpern ibid p353
- Application of Surface Analysis to the Study of the Microbial
Corrosion of Stainless Steel C.R.Clayton ECASIA 97 Eds.,
I.Olefjord, L.Nyborg and D.Briggs John Wiley and Sons New York
(1997), p21
- A Surface Analytical Study of the Role of Nitrogen in Oxyanion
Formation and Incorporation During Aqueous Corrosion of Nitride
Surfaces, M.E.Monserrat, G.P.Halada, C.R.Clayton and J.D.Demaree in
Passivity and Its Breakdown eds., P.M.Natishan et al. The
Electrochemical Society, Pennington N.J. (19
- p 357
- The Effect of Acetone on the Corrosion Characteristics of
AA2024-T3 in a Mist of 0.5M NaCl S.V.Kagwade and C.R.Clayton ibid
p631
- Photochemical Reaction of Organics on Copper and Copper-
Containing Aluminium Alloys and Constituent Intermetallic
Particles, ,C.R.Clayton, G.P.Halada and S.V.Kagwade Critical
Factors in Localized Corrosion III Jerome Kruger 70th Birthday
symposium, The Electrochemical Society, Pennington N.J (1999), p130
- Spatially resolved Microchemical Analysis of Chromate
Conversion Coated Aluminium Alloys and Constituent Intermetallic
Particle Analogues G.P.Halada, C.R.Clayton, M.J.Vasquez,
J.R.Kearns, M.W.Kendig, S.L.Jeanjaquet, G.G.Peterson, G.Shea
McCarthy, G.L.Carr, G.P.Williams and L.M. Carr Critical Factors in
Localized Corrosion III Jerome Kruger 70th Birthday symposium, The
Electrochemical Society, Pennington N.J (1999), p150
- Synthesis of Hard Nitride Coatings by Ion Beam Assisted
Deposition, J.D.Demaree, C.G.Fountzoulas, C.W.Hubbard, C.R.Clayton,
G.P.Halada and M.E.Monserrat in Proc. of the Fall Meeting of the
Materials Research Society, Boston December1-5,(1997), (in press)
- Effect of the Evaporation temperature of an Organic Precursor
on the Properties of Silicon Containing Diamond-like Carbon (Si-
DLC) Coatings synthesized by Ion Beam Deposition (IBAD)
C.R.Clayton, M.E.Monserrat ,G.P.Halada, C.G.Fountzoulas and
J.K.Hirvonen in Proc XII International Conference on Ion
Implantation Technology Kyoto Japan 1998 Editors J.Matsuo,
G.Takaoka and I.Yamada p 885 IEEE Piscataway NJ (1999).
- On the Bipolar Mechanism for Chromate-induced Repassivation of
Active Sites on Chromate Conversion Coated Aluminum Alloys, C.R.
Clayton,G.P.Halada, D.Chidambaram and M.J.Vasquez in Passivity and
Localized Corrosion Eds., M.Seo. B.MacDougall, H.Takahashi and
R.G.Kelly , Proc Vol 99-27 Electrochem. Soc. Pennington NJ (2000), p
249
60) Hydrophobicity and Structural Stability During Aging of
Chromate Conversion Coatings on Al Alloys C.R.Clayton, G.P.Halada,
M.J.Vasquez, J.R.Kearns, D.Chidambaram and R.D.Granata ibid p 290
- Effects of Aging on Chromate Conversion Coatings on
Intemetallic Constituents of AA2024-T3, Vasquez MJ, Halada GP,
Clayton CR, Longtin JP, in Corrosion and Corrosion Prevention of
Low Density Metals and Alloys, 198th Meeting of the Electrochemical
Society, Buchheit Eds, 2000-2, The Electrochemical Society,
Pennington, NJ. (2000).
- Composition of Chromate Conversion Coatings on Thin Films
Anologs of Intermetallic Constituents in AA2024-T3, Vasquez MJ,
Clayton CR, Halada GP, Longtin JP, in Corrosion and Corrosion
Prevention of Low Density Metals and Alloys, 198th Meeting of the
Electrochemical Society, Buchheit Eds, 2000-2, The Electrochemical
Society, Pennington, NJ. (2000).
- Effect of Surface Pretreatments on Chromate Conversion
Coatings, Chidambaram D, Clayton CR, Halada GP, in State-of-the-Art
Application of Surface and Interface Analysis Methods to
Environmental Material Interactions: 199th Meeting of the
Electrochemical Society, Baer DR, Clayton CR, Halada GP, Davis GD,
Eds, 2001-1, The Electrochemical Society, Pennington, NJ. (2001).
- Studies on the Repassivation Behavior of Aluminum Exposed to
Dichromate Solution, Chidambaram D, Clayton CR, Halada GP, in State-
of-the-Art Application of Surface and Interface Analysis Methods to
Environmental Material Interactions: 199th Meeting of the
Electrochemical Society, Baer DR, Clayton CR, Halada GP, Davis GD,
Eds, PV 2001-5, The Electrochemical Society, Pennington, NJ.
(2001), p. 282.
- Novel techniques for the investigation of long-term photo-
degradation of multi-layer polymer coatings, Keene L, Clayton CR,
Halada G, et al., in State-of-the-Art Application of Surface and
Interface Analysis Methods to Environmental Material Interactions:
199th Meeting of the Electrochemical Society, Baer DR, Clayton CR,
Halada GP, Davis GD, Eds, 2001-1, The Electrochemical Society,
Pennington, NJ. (2001), p. 197-206,
- Study of the Structure and Formation of Chromate Conversion
Coatings (CCC) on Thin Film Analogs of Copper-Containing
Intermetallic Constituents in AA2024-T3, Vasquez MJ, Halada GP,
Clayton CR, Longtin JP, in State-of-the-Art Application of Surface
and Interface Analysis Methods to Environmental Material
Interactions: 199th Meeting of the Electrochemical Society, Baer
DR, Clayton CR, Halada GP, Davis GD, Eds, 2001-1, The
Electrochemical Society, Pennington, NJ. (2001).
- On the electrochemical behavior of dichromate and molybdate
treated intermetallic particles present in AA2024-T3, Chidambaram
D, Clayton CR, Halada GP, in Proceedings - Electrochemical Society,
Buchheit RG, Shaw BA, Moran JP, Eds, 2000-23, The Electrochemical
Society (2001), p. 69-78
- Composition of surface treated thin film analogs of
intermetallic constituents in AA2024-T3, Vasquez MJ, Halada GP,
Clayton CR, Longtin JP, in Proceedings - Electrochemical Society,
Buchheit RG, Shaw BA, Moran JP, Eds, 2000-23, The Electrochemical
Society (2001), p. 57-68,
- Effects of aging on chromate conversion coatings formed on
AA2024-T3 and some intermetallic constituents, Vasquez MJ, Halada
GP, Clayton CR, Longtin JP, in Proceedings - Electrochemical
Society, Buchheit RG, Shaw BA, Moran JP, Eds, 2000-23, The
Electrochemical Society (2001), p. 101-13,
- nvestigation of pitting phenomena beneath multi-layer
polymeric coatings, Keene L, Clayton CR, Halada GP, et al., in
Corrosion and Corrosion Protection: 200th Meeting of The
Electrochemical Society, Sinclair JD, Kalman E, Kendig MW, et al.,
Eds, 2001-22, The Electrochemical Society, Pennington, NJ. (2001),
p. 565-72,
- Towards the development of environmentally-friendly corrosion
resistant coatings for depleted uranium-0.75 wt% titanium alloy,
Clayton CR, Chidambaram D, Roeper DF, Halada GP, in Critical
Factors in Localized Corrosion IV: The 202nd Meeting of The
Electrochemical Society., Virtanen S, Schmuki P, Frankel GS, Eds,
2002-24, The Electrochemical Society, Pennington, NJ. (2002), p.
572-82,
- The Role of Fluoride Compounds in the Formation of Chromate
Conversion Coatings on Aluminum Alloys, Chidambaram D, Clayton CR,
in Corrosion and Corrosion Prevention of Low Density Metals and
Alloys - II, 204th Meeting of the Electrochemical Society, Buchheit
RG, Kelly RG, Shaw BA, Missert N, Eds, PV2003-X (To be published),
The Electrochemical Society, Pennington, NJ (2004).
Thesis Advisement:
Ph.D. Theses:
S.B.Agarwal 1979 Corrosion Behaviour of Ni-Implanted Steel
K.Doss 1985 A New Model for the Passivity of Stainless Steels
Y-F Wang 1988 Modification of The Passivity of Iron-based Alloys Through Ion Implantation
M.A.Helfand 1990 Variable Angle XPS Studies of Passive Ni, Cr and Ni-20P-XCr
D.Kim 1992 A Study of The Effect of Nitrogen and Molybdenum in The Corrosion Inhibition of Austenitic Stainless Steel
G.P.Halada 1993 A Surface Study of the Role of Bipolarity and Intermetallic Bonding in the Mechanism of the Passivity of Nitrogen Alloyed Steel
G.Chen 1996 An XPS Study of the Passivity of Stainless Steels Influenced by Sulphate-Reducing Bacteria
S.V.Kagwade 1997 Surface Analytical and Electrochemical Studies of Aircraft Alloy Pretreatments and Their Influence on Corrosion
J.R.Kearns 1999 A Model of the Interfacial Processes Inhibiting The Environmental Degradation of Al-Cu Alloys
C.J.Dodge 1999 Structural Characterization of a Ternary Fe(III)-U(VI)-Citrate Complex
M. J. Vasquez 2002 The Structure and Composition of Chromate Conversion Coatings Formed on Al-Cu Alloy AA2024-T3 And Thin Film Analogs of Constituent Intermetallic Compounds
D. Chidambaram 2003 Surface Chemistry and Corrosion Behavior of Aluminum-Copper Systems: Air Formed Films to Complex Conversion Coatings
L.T.Keene 2005 Physicochemical Characterization and Failure Analysis of Military Coating Systems
D.Roeper 2006 The Development of an Environmentally friendly protective Coating for Dupleted Uranium-07.5 wt% Titanium Alloy
M.S. Theses:
M.R.Dorfman 1979 A Study of The Cavitation Behaviour of thermal Sprayed Coatings
J.Javadpour 1983 Electrochemical and TEM Studies of Laser Surface Melted FeAl Bronzes
W-K Chan 1984 Modification of The Localized Corrosion Behaviour of AISI 52100 Steel by Ion Implantation
S-P Jeng 1984 Surface Carburization of Pure Cr and Fe Under Low energy Inert Gas Ion Implantation
H-C Hua 1987 ESCA Studies of Interface of the Functional Polymer and FPL Etched 2024-T3 Clad Aluminum
L.S.Rosenzweig 1987 The Influence of Nitrogen on the Passivity of 18-8 and 317LX Stainless Steel
M.A.Helfand 1987 Passivity of Amorphous Ni-20P and C0-20P Alloys
K.G.Martin 1988 Effect of Temperature on The Corrosion Resistance Nitrogen Bearing AL6X and 904L Stainless Steels
M.Oversluizen 1988 Preliminary Studies on The Influence of Surface Segregated Nitride on The Anodic Behaviour of Pure Metals and Stainless Steels
F.Tsai 1988 XPS Studies of Passive Films Formed in Borate Solution of pH 8.4: The Effects of XO4n- Oxyanions
R.D.Willenbruch 1989 An Electrochemical Study of The Formation and The Influence of Surface Nitrides on The Anodic Kinetics of Transition Elements and Stainless Steels at Room Temperature and 40 degrees Celcius
W.E.Flugrath 1993 XPS Studies of Benzotriazole Bonding on Copper
R.A.Sadowski 1995 The Design and Implementation of an Ultra High Vacuum Surface Characterization Facility for The Analysis of Biologically Exposed Samples
G.E.French 1998 A Surface Analytical Study of the Attachment of Bacteria to Metals
D. Chidambaram 2000 Evaluation of electrochemical behavior of thermal sprayed coatings
L. T. Keene 2001 Frequency domain digital image correlation a novel application to the detection of environmental degradation of chemical agent resistant coatings
Journal Editing:
- Editorial Board Member: Materials Chemistry and Physics.
Elsevier Sequoia. (1985- 92)
- Advisory Editor: Soviet Surface Engineering and Applied
Electrochemistry. Allerton Press, N.Y. (1984-present)
- Advisory Editor: Boshuku Gijutsu (Corrosion Eng.). Allerton
Press, N.Y. (1987- present)
- Editorial Advisory Board: Critical Reviews in Surface
Chemistry, CRC Press Inc. (1992-1998)
Conference Proceedings Editing:
- Corrosion of Metals Processed by Directed Energy Beams,
Eds., C.R. Clayton and C.M. Preece, TMS-AIME, New York, (1982).
- Fundamental Aspects of Corrosion Protection by Surface
Modification, Eds., E. McCafferty, C.R. Clayton and J. Oudar,
Electrochemical Society, Pennington, NJ (1984).
- Ion Implantation and Ion Beam Processing of Materials,
Eds., G.K. Hubler, O.W. Holland, C.R. Clayton and C.W. White,
Elsevier, NY, (1984).
- Application of Surface Analysis Methods to
Environmental/Material Interactions, Eds.,D.R.Baer,C.R.Clayton and
G.D.Davis, Electrochemical Society, Pennington, NJ (1991)
- Corrosion, Electrochemistry and Catalysis of Metastable
Metals and Intermetallics, Eds., C.R.Clayton and K. Hashimoto
Electrochemical Soc., Pennington, NJ (1994)
- Advances in Coatings Technologies for Corrosion & Wear
Resistant Coatings, Eds., A.R.Srivatsa, C.R.Clayton and
J.K.Hirvonen TMS-AIME Warrenton Pa (1995).
- Advances in Coatings Technologies for Surface Engineering
Eds., C.R.Clayton, J.K.Hirvonen and A.R. Srivatsa, TMS-AIME
Warrenton Pa (1997)
- State of the Art Application of Surface and Interface
Analysis Methods to Environmental Material Interactions,
Eds.,D.R.Baer, C.R.Clayton, G.D.Davis and G. P. Halada,
Electrochemical Society, Pennington, NJ (2001)
Co-Organizer for the following symposia:
- Corrosion Resistance of Ion Implanted and Laser Processed
Materials TMS-AIME, Louisville, KY, October 1981.
- Fundamental Aspects of Corrosion Protection by Surface
Modification, Co-sponsored by the Electrochemical Society and the
European Federation of Corrosion, Washington, DC, October. 1983.
- Implantation and Ion Beam Processing of Materials,
Materials Research Society, Boston, November. 1983.
- Application of Surface Analysis Methods to Environmental/
Material Interactions (I) co-sponsored by the Electrochemical
Society and American Vacuum Society, Seattle, Washington, October.
1990.
- Application of Surface Analysis Methods to
Environmental/Materials Interactions (II) co-sponsored by the
Electrochemical Society and the American Vacuum Society, San
Francisco, California, May 1994.
- Program Chairman 1986-87 A.S.M. Long Island Chapter.
- Corrosion, Electrochemistry and Catalysis of Metastable
Metals and Intermetallics, co-sponsored by the Electrochemistry
Society and the Electrochemical Society of Japan, Honolulu, Hawaii
May 1993
- Advances in Coatings Technologies for Corrosion and Wear
Resistance 124th TMS Annual Meeting, Las Vegas, Nevada, February
1995.
- Advances in Coatings Technologies for Surface Engineering
126th TMS Annual Meeting, Orlando Florida, February 1997.
- State of the Art Application of Surface and Interface
Analysis Methods to Environmental Material Interactions: A
Symposium in Honor of James Castle's 65th Birthday. Washington, DC
March 2001
Book Reviews:
- Material Science and Engineering: An Introduction by
William D. Callister, Jr., John Wiley and Sons in Materials Science
and Engineering, p. 94, 266 (l987).
Journal Reviewing:
- J. Electrochemical Society
- NACE Corrosion
- Corrosion
- J. Applied Electrochemistry
- Surface and Interface Analysis
- J. Non Crystalline Materials
- Nuclear Instruments and Materials
- J. Vacuum Science and Technology
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